Advances in Organometallic Chemistry, 7 by F G A Stone; Robert West

By F G A Stone; Robert West

ADVANCES ORGANOMETALLIC CHEMISTRY V 7.

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A novel and very reactive type directly derivable from the parent type, is tris(trimethy1sily1)silyllithium. , dr-pr bonding. Historically, it is interesting to note that a related type was prepared about 40 years ago, and its structure was recently established, with F. K. Cartledge, as tetrakis(triphenylstannyl)stannane, (Ph3Sn),Sn. More recently G. van der Kerk and co-workers have prepared an unusually interesting series of related types. One among them, (Ph,Pb),Pb, is of particular interest because it is the first catenated triplumbane type reported, and diplumbanes are generally unstable.

40. Rochow, E. , Hurd, D. , and Lewis, R. ” Wiley, New York, 1957. 41. Shirley, D. , Org. Reactions 8, 28 (1954). 42. Sommer, L. ” McGraw-Hill, New York, 1965. 43. West, C. , Natl. Acad. -Natl. Res. Council, Reprint Circ. Ser. 24 (1922). 52 HENRY G I L M A N 44. , Quart. Rev. 13,116 (1959). 45. Wright, G . , Ind. Eng. Chem. 40,1517 (1948). 46. Wright, G . , in “Methoden der organischen Chemie” (E. ). Thieme, Stuttgart, Germany, 1968. Oxidative=Addition Reactions of d8 Complexes JAMES P. COLLMAN' Department of Chemistry, University of North Carolina Chapel Hill, North Carolina W A R R E N 'R.

And Beatty, H. , in “Organic Chemistry-An Advanced Treatise” (H. ), Vol. 11, pp. 1806-1821. Wiley, New York, 1947. 4. Cartledge, F. , in “Characterization of Organometallics” (M. ), Wiley, New York, 1968. 5. Corey, E. , and Posner, G. , J . A m . Chem. Soc. 89, 3911 (1967). 6. Dessy, R. , Chem. Eng. News 41,142 (1963). 7. , 1960. Another classical work is the three-volume compendium by V. Bafant, V. , and J. ” Czechoslovak Acad. Sci. Publ. House, Prague, 1965. T h e most comprehensive series of volumes in organometallic chemistry is by A.

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